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Potentiometric strip cell based on carbon nanotubes as transducer layer: toward low-cost decentralized measurements.

Authors :
Rius-Ruiz FX
Crespo GA
Bejarano-Nosas D
Blondeau P
Riu J
Rius FX
Source :
Analytical chemistry [Anal Chem] 2011 Nov 15; Vol. 83 (22), pp. 8810-5. Date of Electronic Publication: 2011 Oct 21.
Publication Year :
2011

Abstract

In this study, we developed a potentiometric planar strip cell based on single-walled carbon nanotubes that aims to exploit the attributes of solid-contact ion-selective electrodes for decentralized measurements. That is, the ion-selective and reference electrodes have been simultaneously miniaturized onto a plastic planar substrate by screen-printing and drop-casting techniques, obtaining disposable strip cells with satisfactory performance characteristics (i.e., the sensitivity is 57.4 ± 1.3 mV/dec, the response time is ≤30 s within the linear range from log a(K+) = -5 to -2, and the limit of detection is -6.5), no need of maintenance during long dry storage, quick signal stabilization, and light insensitivity in short-term measurements. We also show how the new potentiometric strip cell makes it possible to perform decentralized and rapid determinations of ions in real samples, such as saliva or beverages.

Details

Language :
English
ISSN :
1520-6882
Volume :
83
Issue :
22
Database :
MEDLINE
Journal :
Analytical chemistry
Publication Type :
Academic Journal
Accession number :
21961835
Full Text :
https://doi.org/10.1021/ac202070r