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An organometallic sandwich lanthanide single-ion magnet with an unusual multiple relaxation mechanism.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2011 Dec 07; Vol. 133 (48), pp. 19286-9. Date of Electronic Publication: 2011 Nov 11. - Publication Year :
- 2011
-
Abstract
- A dysprosium(III) sandwich complex, [Dy(III)(COT″)(2)Li(THF)(DME)], was synthesized using 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion (COT″). The complex behaves as a single-ion magnet and demonstrates unusual multiple relaxation modes. The observed relaxation pathways strongly depend on the applied static dc fields.<br /> (© 2011 American Chemical Society)
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 133
- Issue :
- 48
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 22032273
- Full Text :
- https://doi.org/10.1021/ja207891y