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First magnetostructural study on a heterodinuclear 2,2'-bipyrimidine-bridged complex.
- Source :
-
Inorganic chemistry [Inorg Chem] 2011 Dec 19; Vol. 50 (24), pp. 12405-7. Date of Electronic Publication: 2011 Nov 17. - Publication Year :
- 2011
-
Abstract
- The use of the [ReCl(4)(bpym)] precursor as a ligand toward the fully solvated nickel(II) metal ion affords the first example of a 2,2'-bipyrimidine-bridged Re(IV)-Ni(II) complex, [ReCl(4)(μ-bpym)NiBr(2)(H(2)O)(2)] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies.<br /> (© 2011 American Chemical Society)
Details
- Language :
- English
- ISSN :
- 1520-510X
- Volume :
- 50
- Issue :
- 24
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 22092100
- Full Text :
- https://doi.org/10.1021/ic202088s