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Water oxidation catalyzed by a new tetracobalt-substituted polyoxometalate complex: [{Co4(μ-OH)(H2O)3}(Si2W19O70)]11-.

Authors :
Zhu G
Geletii YV
Kögerler P
Schilder H
Song J
Lense S
Zhao C
Hardcastle KI
Musaev DG
Hill CL
Source :
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2012 Feb 21; Vol. 41 (7), pp. 2084-90. Date of Electronic Publication: 2011 Dec 21.
Publication Year :
2012

Abstract

A new polyoxometalate of earth adundant elements [{Co(4)(μ-OH)(H(2)O)(3)}(Si(2)W(19)O(70))](11-) has been synthesized, characterized and shown to be a water oxidation catalyst. The initial catalytic complex is unstable and slowly undergoes hydrolysis. The hydrolysis products have been isolated and characterized, and their catalytic water oxidation activity is assessed.

Details

Language :
English
ISSN :
1477-9234
Volume :
41
Issue :
7
Database :
MEDLINE
Journal :
Dalton transactions (Cambridge, England : 2003)
Publication Type :
Academic Journal
Accession number :
22186630
Full Text :
https://doi.org/10.1039/c1dt11211b