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Water oxidation catalyzed by a new tetracobalt-substituted polyoxometalate complex: [{Co4(μ-OH)(H2O)3}(Si2W19O70)]11-.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2012 Feb 21; Vol. 41 (7), pp. 2084-90. Date of Electronic Publication: 2011 Dec 21. - Publication Year :
- 2012
-
Abstract
- A new polyoxometalate of earth adundant elements [{Co(4)(μ-OH)(H(2)O)(3)}(Si(2)W(19)O(70))](11-) has been synthesized, characterized and shown to be a water oxidation catalyst. The initial catalytic complex is unstable and slowly undergoes hydrolysis. The hydrolysis products have been isolated and characterized, and their catalytic water oxidation activity is assessed.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 41
- Issue :
- 7
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 22186630
- Full Text :
- https://doi.org/10.1039/c1dt11211b