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Contrasting reductions of group 14 metal(II) chloride complexes: synthesis of a β-diketiminato tin(I) dimer.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Mar 04; Vol. 48 (19), pp. 2504-6. Date of Electronic Publication: 2012 Jan 26. - Publication Year :
- 2012
-
Abstract
- Reductions of the β-diketiminato group 14 metal(II) chloride complexes, [((But)MesNacnac)ECl] ((But)MesNacnac = [(MesNCBu(t))(2)CH](-); Mes = mesityl; E = Ge, Sn or Pb), with a magnesium(I) dimer have led to differing outcomes, which include the formation of the first β-diketiminato group 14 metal(I) dimer, [{((But)MesNacnac)Sn}(2)].<br /> (This journal is © The Royal Society of Chemistry 2012)
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 48
- Issue :
- 19
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 22281528
- Full Text :
- https://doi.org/10.1039/c2cc18086c