Back to Search Start Over

A bifunctional catalyst for carbon dioxide fixation: cooperative double activation of epoxides for the synthesis of cyclic carbonates.

Authors :
Ema T
Miyazaki Y
Koyama S
Yano Y
Sakai T
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 May 11; Vol. 48 (37), pp. 4489-91. Date of Electronic Publication: 2012 Mar 30.
Publication Year :
2012

Abstract

We have developed a very active bifunctional porphyrin catalyst showing a high turnover number (TON = 103,000) for the synthesis of cyclic carbonates from CO(2) and epoxides under solvent-free conditions.<br /> (This journal is © The Royal Society of Chemistry 2012)

Details

Language :
English
ISSN :
1364-548X
Volume :
48
Issue :
37
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
22460201
Full Text :
https://doi.org/10.1039/c2cc30591g