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catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl-ato-κ(4)O(1),O(2):O(2),O(2')].

Authors :
Li YF
Gao Y
Xu Y
Qin XL
Gao WY
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Apr 01; Vol. 68 (Pt 4), pp. m445. Date of Electronic Publication: 2012 Mar 17.
Publication Year :
2012

Abstract

In the title compound, [Cu(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Cu(OH(2))(3)O(4) cluster with one carboxyl-ate group of the furan-2,5-dicarboxyl-ate ligand. Adjacent chains are linked by O(water)-H⋯O hydrogen-bonding inter-actions. The Cu(OH(2))(3)O(4) cluster displays a penta-gonal bipyrimadal geometry with two weak coordinations [Cu-O(furan) = 2.790 (2) Å) and Cu-O(carboxyl-ate) = 2.684 (2) Å] and two water mol-ecules located in axial positions.

Details

Language :
English
ISSN :
1600-5368
Volume :
68
Issue :
Pt 4
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
22589817
Full Text :
https://doi.org/10.1107/S1600536812010161