Back to Search Start Over

Bis[2-(2-oxoindolin-3-yl-idene)-N-phenylhydrazinecarbothio-amidato-κ(3)O,N(2),S]nickel(II) dimethyl-formamide monosolvate.

Authors :
Ali AQ
Eltayeb NE
Teoh SG
Salhin A
Fun HK
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 May 01; Vol. 68 (Pt 5), pp. m538-9. Date of Electronic Publication: 2012 Apr 04.
Publication Year :
2012

Abstract

The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex mol-ecule and one disordered dimethyl-formamide solvent mol-ecule. The Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by two N, two O and two S atoms. An intra-molecular C-H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked through inter-molecular N-H⋯S, N-H⋯O, C-H⋯N, C-H⋯O and C-H⋯S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C-H⋯π inter-actions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio.

Details

Language :
English
ISSN :
1600-5368
Volume :
68
Issue :
Pt 5
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
22590064
Full Text :
https://doi.org/10.1107/S1600536812012834