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Quest for highly porous metal-metalloporphyrin framework based upon a custom-designed octatopic porphyrin ligand.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Jul 21; Vol. 48 (57), pp. 7173-5. Date of Electronic Publication: 2012 Jun 13. - Publication Year :
- 2012
-
Abstract
- A porous metal-metalloporphyrin framework, MMPF-2, has been constructed from a custom-designed octatopic porphyrin ligand, tetrakis(3,5-dicarboxyphenyl)porphine, that links a distorted cobalt trigonal prism secondary building unit. MMPF-2 possesses permanent microporosity with the highest surface area of 2037 m(2) g(-1) among reported porphyrin-based MOFs, and demonstrates a high uptake capacity of 170 cm(3) g(-1) CO(2) at 273 K and 1 bar.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 48
- Issue :
- 57
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 22691954
- Full Text :
- https://doi.org/10.1039/c2cc33118g