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Chemoselective transfer hydrogenation to nitroarenes mediated by cubane-type Mo3S4 cluster catalysts.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2012 Jul 27; Vol. 51 (31), pp. 7794-8. Date of Electronic Publication: 2012 Jun 18. - Publication Year :
- 2012
-
Abstract
- Chemoselective cubes: Cubane-type [Mo(3)S(4)X(3)(dmpe)(3)](+) clusters (dmpe = 1,2-(bis)dimethylphosphinoethane), in combination with an azeotropic 5:2 mixture of HCOOH and NEt(3) as the reducing agent, act as selective cluster catalysts (X = H) or precatalysts (X = Cl) for the transfer hydrogenation of functionalized nitroarenes, without the formation of hazardous hydroxylamines.<br /> (Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 51
- Issue :
- 31
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 22711684
- Full Text :
- https://doi.org/10.1002/anie.201202584