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{1,6}-Transannular catalytic asymmetric Gosteli-Claisen rearrangement.
- Source :
-
Organic letters [Org Lett] 2012 Aug 17; Vol. 14 (16), pp. 4114-7. Date of Electronic Publication: 2012 Aug 03. - Publication Year :
- 2012
-
Abstract
- The first uncatalyzed and [Cu(R-box)L(2)](SbF(6))(2)-catalyzed {1,6}-transannular Gosteli-Claisen rearrangement of cyclic 2-alkoxycarbonyl-substituted allyl vinyl ethers to afford medium- and large-sized carbacycles is disclosed.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 14
- Issue :
- 16
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 22860898
- Full Text :
- https://doi.org/10.1021/ol3017676