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Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2012 Aug 28; Vol. 41 (36), pp. 10930-3. - Publication Year :
- 2012
-
Abstract
- Magnesium-aryloxide and -amide compounds supported by amidinate ligands are accessible in two-steps from a suitable Grignard reagent. Both species are active for the dimerization of benzaldehyde. The slower initiation by the aryloxide was exploited in the isolation of a bis-mesitylaldehyde adduct.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 41
- Issue :
- 36
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 22886325
- Full Text :
- https://doi.org/10.1039/c2dt31442h