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Poly[(μ(5)-2,2'-bipyridine-5,5'-dicarboxyl-ato)lead(II)].

Authors :
Sertçelik M
Caylak Delibaş N
Cevik S
Necefoğlu H
Hökelek T
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Sep 01; Vol. 68 (Pt 9), pp. m1196-7. Date of Electronic Publication: 2012 Aug 23.
Publication Year :
2012

Abstract

In the title polymeric compound, [Pb(C(12)H(6)N(2)O(4))](n), the Pb(II) cation, located on a mirror plane, is N,N'-chelated by a 2-2'-bipyridine-5,5'-dicarboxyl-ate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N(2)O(6) geometry. The carboxylate groups bridge the Pb(II) cations, forming a three-dimensional polymeric structure. The carboxyl-ate group is twisted away from the attached pyridine ring by 11.4 (3)°.

Details

Language :
English
ISSN :
1600-5368
Volume :
68
Issue :
Pt 9
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
22969486
Full Text :
https://doi.org/10.1107/S1600536812035647