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[{Fe(CO)3}4{SnI}6I4]2-: the first bimetallic adamantane-like cluster.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2012 Oct 22; Vol. 18 (43), pp. 13600-4. Date of Electronic Publication: 2012 Sep 17. - Publication Year :
- 2012
-
Abstract
- Show some metal: the first bimetallic adamantane-like cluster, [{Fe(CO)(3)}(4){SnI}(6)I(4)](2-), was prepared by an ionic-liquid-based synthesis. The valence states of iron and tin were verified based on bond-length considerations, FT-IR and (119)Sn Mössbauer spectroscopy, as well as with DFT calculations.<br /> (Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 18
- Issue :
- 43
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 22987543
- Full Text :
- https://doi.org/10.1002/chem.201202683