Back to Search Start Over

(Acetato-κO)(acetato-κO,O')bis-(1,3-diazinane-2-thione-κS)cadmium(II).

Authors :
Mahmood R
Ghulam Hussain S
Fettouhi M
Isab AA
Ahmad S
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Nov 01; Vol. 68 (Pt 11), pp. m1352-3. Date of Electronic Publication: 2012 Oct 13.
Publication Year :
2012

Abstract

In the title complex, [Cd(CH(3)COO)(2)(C(4)H(8)N(2)S)(2)], the Cd(II) cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetra-hydro-pyrimidine-2(1H)-thione]. The Cd(II) coordination is augmented by one considerably longer Cd-O bond of 2.782 (3) Å to a carboxyl-ate O atom. The resulting coordination polyhedron around the Cd(II) cations can be described as a highly distorted octa-hedron. The Diaz ligand and the acetate anions are linked by N-H⋯O hydrogen-bonding inter-actions.

Details

Language :
English
ISSN :
1600-5368
Volume :
68
Issue :
Pt 11
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
23284338
Full Text :
https://doi.org/10.1107/S1600536812041852