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Reactions of difluorocarbene with organozinc reagents.
- Source :
-
Organic letters [Org Lett] 2013 Feb 15; Vol. 15 (4), pp. 917-9. Date of Electronic Publication: 2013 Jan 31. - Publication Year :
- 2013
-
Abstract
- Reactions of difluorocarbene with benzyl and alkylzinc halides leading to fluorinated organozinc species have been described. The generated α-difluorinated organozinc reagents are reasonably stable in solution and can be quenched with external electrophiles (iodine, bromine, proton), affording compounds containing the CF(2) fragment.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 15
- Issue :
- 4
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 23368906
- Full Text :
- https://doi.org/10.1021/ol400122k