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The influence of the secondary relaxation processes on the structural relaxation in glass-forming materials.

Authors :
Khamzin AA
Popov II
Nigmatullin RR
Source :
The Journal of chemical physics [J Chem Phys] 2013 Jun 28; Vol. 138 (24), pp. 244502.
Publication Year :
2013

Abstract

In the frame of fractional-kinetic approach, the model of the structural α-relaxation in the presence of the secondary β-relaxation processes is suggested. The model is based on the rigorous bond between β-processes with α-process and leads to the generalized and justified expression for the complex dielectric permittivity (CDP). It allows to form a new sight on the problem of the fitting of multi-peak structure of the dielectric loss spectra in glass-forming materials. The consistency of the CDP expressions obtained is based on a good fit of experimental data for binary methanol-water mixtures.

Details

Language :
English
ISSN :
1089-7690
Volume :
138
Issue :
24
Database :
MEDLINE
Journal :
The Journal of chemical physics
Publication Type :
Academic Journal
Accession number :
23822251
Full Text :
https://doi.org/10.1063/1.4811663