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The influence of the secondary relaxation processes on the structural relaxation in glass-forming materials.
- Source :
-
The Journal of chemical physics [J Chem Phys] 2013 Jun 28; Vol. 138 (24), pp. 244502. - Publication Year :
- 2013
-
Abstract
- In the frame of fractional-kinetic approach, the model of the structural α-relaxation in the presence of the secondary β-relaxation processes is suggested. The model is based on the rigorous bond between β-processes with α-process and leads to the generalized and justified expression for the complex dielectric permittivity (CDP). It allows to form a new sight on the problem of the fitting of multi-peak structure of the dielectric loss spectra in glass-forming materials. The consistency of the CDP expressions obtained is based on a good fit of experimental data for binary methanol-water mixtures.
Details
- Language :
- English
- ISSN :
- 1089-7690
- Volume :
- 138
- Issue :
- 24
- Database :
- MEDLINE
- Journal :
- The Journal of chemical physics
- Publication Type :
- Academic Journal
- Accession number :
- 23822251
- Full Text :
- https://doi.org/10.1063/1.4811663