Rational design of boradiazaindacene (BODIPY)-based functional molecules.

Authors :: Gupta M
Mula S
Tyagi M
Ghanty TK
Murudkar S
Ray AK
Chattopadhyay S
Source :: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2013 Dec 23; Vol. 19 (52), pp. 17766-72. Date of Electronic Publication: 2013 Nov 28.
Publication Year :: 2013
Abstract: Three boradiazaindacene (BODIPY) dyes with different-coloured (greenish-yellow, orange and red) fluorescence and good Stokes shifts were synthesised starting from the greenish-yellow BODIPY dye PM546. The high Stokes shifts of the dyes are due to the release of the steric strain in their excited states relative to that in the highly twisted ground states. One of these compounds might be a useful water-soluble fluorophore, whereas the other two are promising H(+) sensors.<br /> (Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)