Regioselective prenylation of bromocarbazoles by palladium(0)-catalysed cross coupling--synthesis of O-methylsiamenol, O-methylmicromeline and carquinostatin A.

Authors :: Thomas C
Kataeva O
Schmidt AW
Knölker HJ
Source :: Organic & biomolecular chemistry [Org Biomol Chem] 2014 Feb 14; Vol. 12 (6), pp. 872-5.
Publication Year :: 2014
Abstract: We describe the regioselective prenylation of 3-bromocarbazole by palladium(0)-catalysed cross coupling with a prenylstannane or a prenylboronate. The procedure is applied to the synthesis of precursors for biologically active carbazole alkaloids.

Subjects :: Carbazoles chemical synthesis
Catalysis
Molecular Structure
Stereoisomerism
Carbazoles chemistry
Organometallic Compounds chemistry
Palladium chemistry

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