Bandgap engineered and high monochromatic electrochemiluminescence from dual-stabilizers-capped CdSe nanocrystals with practical application potential.

The development of electrochemiluminescence (ECL) emitters over a broad spectrum of wavelengths is anticipated for the multiplexed ECL sensing and diagnostic application. Herein, a facile dual-stabilizers-capped strategy was developed for synthesizing a series of water-soluble CdSe nanocrystals (NCs) with strong, bandgap engineered and monochromatic ECL emissions in greenish region. The linkage of surface cadmium atoms to the dual stabilizers, mercaptopropionic acid and sodium hexametaphosphate, not only can effectively remove the nonradiative surface state and deep surface trap of CdSe NCs for improved ECL efficiency and monochromaticity, but is also favorable for the electrochemical involved electron and hole injection processes for higher ECL intensity. ECL spectra of dual-stabilizers-capped CdSe NCs are narrow and much close to corresponding photoluminescence spectra, which indicates a series of bandgap engineered and monochromatic ECL emitters. The ECL signal of dual-stabilizers-capped CdSe NCs also shows acceptable accuracy and precision for the detection of dopamine concentration in the practical drug (dopamine hydrochloride injection).
(Copyright © 2013 Elsevier B.V. All rights reserved.)