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Copper-catalyzed allylation of α,α-difluoro-substituted organozinc reagents.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2014 Jan 17; Vol. 79 (2), pp. 818-22. Date of Electronic Publication: 2014 Jan 02. - Publication Year :
- 2014
-
Abstract
- A method for the coupling of organozinc reagents, difluorocarbene, and allylic electrophiles is described. The reaction involves insertion of difluorocarbene into the carbon-zinc bond followed by copper-catalyzed allylic substitution.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 79
- Issue :
- 2
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 24432717
- Full Text :
- https://doi.org/10.1021/jo4024705