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Adaptable hetero Diels-Alder networks for fast self-healing under mild conditions.
- Source :
-
Advanced materials (Deerfield Beach, Fla.) [Adv Mater] 2014 Jun 04; Vol. 26 (21), pp. 3561-6. Date of Electronic Publication: 2014 Mar 21. - Publication Year :
- 2014
-
Abstract
- A novel adaptable network based on the reversible hetero Diels-Alder reaction of a cyanodithioester and cyclopentadiene is presented. Reversible between 50-120 °C, the adjustable and self-healing features of the network are evidenced via temperature dependent rheology experiments and repetitive tensile tests whereas the network's chemical structure is explored by temperature dependent (1) H MAS-NMR spectroscopy.<br /> (© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-4095
- Volume :
- 26
- Issue :
- 21
- Database :
- MEDLINE
- Journal :
- Advanced materials (Deerfield Beach, Fla.)
- Publication Type :
- Academic Journal
- Accession number :
- 24659414
- Full Text :
- https://doi.org/10.1002/adma.201306258