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3-Methyl-4,5-di-hydro-oxazolium tetra-phenyl-borate.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2014 Feb 22; Vol. 70 (Pt 3), pp. o325. Date of Electronic Publication: 2014 Feb 22 (Print Publication: 2014). - Publication Year :
- 2014
-
Abstract
- In the cation of the title salt, C4H8NO(+)·C24H20B(-), the C-N bond lengths are 1.272 (2), 1.4557 (19) and 1.4638 (19) Å, indicating double- and single-bond character, respectively. The C-O bond length of 1.3098 (19) Å shows that double-bond character and charge delocalization occurs within the NCO plane of the cation. In the crystal, a C-H⋯π inter-action is present between the methyl-ene H atom of the cation and one phenyl ring of the tetra-phenyl-borate ion. The latter forms an aromatic pocket in which the cation is embedded.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 70
- Issue :
- Pt 3
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 24765023
- Full Text :
- https://doi.org/10.1107/S1600536814003456