Back to Search Start Over

3-Methyl-4,5-di-hydro-oxazolium tetra-phenyl-borate.

Authors :
Tiritiris I
Saur S
Kantlehner W
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2014 Feb 22; Vol. 70 (Pt 3), pp. o325. Date of Electronic Publication: 2014 Feb 22 (Print Publication: 2014).
Publication Year :
2014

Abstract

In the cation of the title salt, C4H8NO(+)·C24H20B(-), the C-N bond lengths are 1.272 (2), 1.4557 (19) and 1.4638 (19) Å, indicating double- and single-bond character, respectively. The C-O bond length of 1.3098 (19) Å shows that double-bond character and charge delocalization occurs within the NCO plane of the cation. In the crystal, a C-H⋯π inter-action is present between the methyl-ene H atom of the cation and one phenyl ring of the tetra-phenyl-borate ion. The latter forms an aromatic pocket in which the cation is embedded.

Details

Language :
English
ISSN :
1600-5368
Volume :
70
Issue :
Pt 3
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
24765023
Full Text :
https://doi.org/10.1107/S1600536814003456