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Visible-light photoredox-catalyzed synthesis of nitrones: unexpected rate acceleration by water in the synthesis of isoxazolidines.
- Source :
-
Organic letters [Org Lett] 2014 Jun 06; Vol. 16 (11), pp. 2872-5. Date of Electronic Publication: 2014 May 08. - Publication Year :
- 2014
-
Abstract
- A new oxidative [3 + 2] cycloaddition of N-substituted hydroxylamines with alkenes was established under visible light photoredox catalysis. This novel protocol provides a rapid, mild, and efficient access to valuable five-membered ring isoxazolidine heterocycles in a concise fashion.
- Subjects :
- Alkenes chemistry
Catalysis
Cyclization
Cycloaddition Reaction
Heterocyclic Compounds chemistry
Light
Molecular Structure
Oxidation-Reduction
Photochemical Processes
Stereoisomerism
Water
Heterocyclic Compounds chemical synthesis
Hydroxylamine chemistry
Isoxazoles chemical synthesis
Isoxazoles chemistry
Nitrogen Oxides chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 16
- Issue :
- 11
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 24810928
- Full Text :
- https://doi.org/10.1021/ol500893g