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Synthesis and molecular structure of an abnormal carbene-gallium chloride complex.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2014 Oct 14; Vol. 43 (38), pp. 14211-4. - Publication Year :
- 2014
-
Abstract
- Low temperature reaction of N-heterocyclic carbene : BEt3 with nBuLi (in THF) initially gives the C4-lithiated N-heterocyclic carbene : BEt3 complex (4), which isomerizes to the C2-lithiated abnormal N-heterocyclic carbene : BEt3 complex (2) in refluxing THF. While reaction of with GaCl3 gives a 4-functionalized N-heterocyclic carbene : GaCl3 adduct (6), reaction of with GaCl3 affords the first abnormal carbene-gallium chloride complexes (5).
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 43
- Issue :
- 38
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 24934096
- Full Text :
- https://doi.org/10.1039/c4dt00933a