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Pd(II)-Catalyzed arylation of unactivated methylene C(sp3)-H bonds with aryl halides using a removable auxiliary.

Authors :
Zhang Q
Yin XS
Zhao S
Fang SL
Shi BF
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Aug 07; Vol. 50 (61), pp. 8353-5.
Publication Year :
2014

Abstract

A Pd(II)-catalyzed arylation of methylene C(sp(3))-H bonds in aliphatic amides directed by our newly developed PIP directing group with aryl iodides/bromides has been achieved. Arylation occurs efficiently with a broad range of aryl halides and amides.

Details

Language :
English
ISSN :
1364-548X
Volume :
50
Issue :
61
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
24943091
Full Text :
https://doi.org/10.1039/c4cc03615h