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Transient substrate-induced catalyst formation in a dynamic molecular network.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2014 Oct 13; Vol. 53 (42), pp. 11346-50. Date of Electronic Publication: 2014 Aug 28. - Publication Year :
- 2014
-
Abstract
- In biology enzyme concentrations are continuously regulated, yet for synthetic catalytic systems such regulatory mechanisms are underdeveloped. We now report how a substrate of a chemical reaction induces the formation of its own catalyst from a dynamic molecular network. After complete conversion of the substrate, the network disassembles the catalyst. These results open up new opportunities for controlling catalysis in synthetic chemical systems.<br /> (© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
- Subjects :
- Biocatalysis
Catalysis
Systems Theory
Combinatorial Chemistry Techniques methods
Subjects
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 53
- Issue :
- 42
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 25169198
- Full Text :
- https://doi.org/10.1002/anie.201403480