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Synthesis and electronic properties of oxidized benzo[1,2-b:4,5-b']dithiophenes.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2014 Oct 03; Vol. 79 (19), pp. 9408-12. Date of Electronic Publication: 2014 Sep 19. - Publication Year :
- 2014
-
Abstract
- Benzo[1,2-b:4,5-b']dithiophenes were oxidized under mild conditions with m-CPBA to yield the corresponding bis-sulfones (or tetraoxides). These sulfones possess red-shifted absorption and emission spectra relative to the parent molecules. Electrochemical analyses reveal that the benzodithiophene molecules are transformed from electron donors to electron acceptors.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 79
- Issue :
- 19
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 25198532
- Full Text :
- https://doi.org/10.1021/jo5017585