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Preparation and properties of self-reinforced cellulose composite films from Agave microfibrils using an ionic liquid.
- Source :
-
Carbohydrate polymers [Carbohydr Polym] 2014 Dec 19; Vol. 114, pp. 537-545. Date of Electronic Publication: 2014 Aug 30. - Publication Year :
- 2014
-
Abstract
- The applications of natural fibers and their microfibrils are increasing rapidly due to their environment benefits, specific strength properties and renewability. In the present work, we successfully extracted cellulose microfibrils from Agave natural fibers by chemical method. The extracted microfibrils were characterized by chemical analysis. The cellulose microfibrils were found to dissolve in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl) to larger extent along with little quantity of undissolved microfibrils. Using this solution, the self-reinforced regenerated cellulose composite films were prepared. The raw fiber, extracted cellulose microfibrils and regenerated cellulose composite films were characterized by FTIR, (13)C CP-MAS NMR, XRD, TGA and SEM techniques. The average tensile strength, modulus and elongation at break of the self-reinforced cellulose composite films were found to be 135 MPa, 8150 MPa and 3.2%, respectively. The high values of tensile strength and modulus were attributed to the self-reinforcement of Agave fibers in their generated matrix. These self-reinforced cellulose biodegradable composite films prepared from renewable source can find applications in packaging field.<br /> (Copyright © 2014 Elsevier Ltd. All rights reserved.)
- Subjects :
- Cellulose chemistry
Ionic Liquids chemistry
Microfibrils chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1879-1344
- Volume :
- 114
- Database :
- MEDLINE
- Journal :
- Carbohydrate polymers
- Publication Type :
- Academic Journal
- Accession number :
- 25263924
- Full Text :
- https://doi.org/10.1016/j.carbpol.2014.08.054