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[Near infrared Cavity enhanced absorption spectroscopy study of NO2O].
- Source :
-
Guang pu xue yu guang pu fen xi = Guang pu [Guang Pu Xue Yu Guang Pu Fen Xi] 2014 Aug; Vol. 34 (8), pp. 2081-4. - Publication Year :
- 2014
-
Abstract
- Using a tunable near infrared external cavity diode laser and a 650 mm long high finesse optical cavity consisting of two highly reflective (R=99.97% at 6561.39 cm(-1)) plan-concave mirrors of curvature radius approximately 1000 mm, a cavity enhanced absorption spectroscopy (CEAS) system was made. The absorption spectra centered at 6561.39 cm(-1) of pure N2O gas and gas mixtures of N2O and N2 were recorded. According to the absorption of N2O at 6561.39 cm(-1) in the cavity, the measured effective absorption path was about 1460 km. The spectra line intensity and line-width of N2O centered at 6561.39 cm(-1) were carefully studied. The relationship between the line-width of absorption spectra and the gas pressure was derived. The pressure broadening parameter of N2 gas for NO2O line centered at 6 561. 39 cm(-1) was deduced and given a value of approximately (0.114 +/- 0.004) cm(-1) x atm(-1). The possibility to detect trace N2O gas in mixture using this CEAS system was investigated. By recording the ab- sorption spectra of N2O gas mixtures at different concentration, the relationship between the line intensity and gas concentration was derived. The minimum detectable absorption was found to be 2.34 x 10(-7) cm(-1) using this cavity enhanced absorption spectroscopy system. And te measurement precision in terms of relative standard deviation (RSD) for N2O is approximately 1.73%, indicating the possibility of using the cavity enhanced absorption spectroscopy system for micro gas N2O analysis in the future.
Details
- Language :
- Chinese
- ISSN :
- 1000-0593
- Volume :
- 34
- Issue :
- 8
- Database :
- MEDLINE
- Journal :
- Guang pu xue yu guang pu fen xi = Guang pu
- Publication Type :
- Academic Journal
- Accession number :
- 25474938