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Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine.
- Source :
-
Chemistry, an Asian journal [Chem Asian J] 2015 Oct; Vol. 10 (10), pp. 2139-42. Date of Electronic Publication: 2015 Feb 05. - Publication Year :
- 2015
-
Abstract
- A novel synthetic route gives access to mesoionic carbene and cyclopropenylidene supported gold chloride complexes. The corresponding cationic MIC-gold complex obtained by chloride abstraction allows for the first transition metal-catalyzed functionalization of both nitrogens of parent hydrazine.<br /> (© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1861-471X
- Volume :
- 10
- Issue :
- 10
- Database :
- MEDLINE
- Journal :
- Chemistry, an Asian journal
- Publication Type :
- Academic Journal
- Accession number :
- 25597889
- Full Text :
- https://doi.org/10.1002/asia.201403408