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Non-centrosymmetric homochiral supramolecular polymers of tetrahedral subphthalocyanine molecules.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2015 Feb 16; Vol. 54 (8), pp. 2543-7. Date of Electronic Publication: 2015 Jan 19. - Publication Year :
- 2015
-
Abstract
- A combination of spectroscopy (UV/Vis absorption, emission, and circular dichroism), microscopy (AFM and TEM), and computational studies reveal the formation of non-centrosymmetric homochiral columnar subphthalocyanine assemblies. These assemblies form through a cooperative supramolecular polymerization process driven by hydrogen-bonding between amide groups, π-π stacking, and dipolar interactions between axial B-F bonds.<br /> (© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 54
- Issue :
- 8
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 25597927
- Full Text :
- https://doi.org/10.1002/anie.201411272