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Mn2FeWO6 : A new Ni3TeO6-type polar and magnetic oxide.

Authors :
Li MR
Croft M
Stephens PW
Ye M
Vanderbilt D
Retuerto M
Deng Z
Grams CP
Hemberger J
Hadermann J
Li WM
Jin CQ
Saouma FO
Jang JI
Akamatsu H
Gopalan V
Walker D
Greenblatt M
Source :
Advanced materials (Deerfield Beach, Fla.) [Adv Mater] 2015 Apr 01; Vol. 27 (13), pp. 2177-81. Date of Electronic Publication: 2015 Feb 11.
Publication Year :
2015

Abstract

Mn(2+)2 Fe(2+)W(6+)O6 , a new polar magnetic phase, adopts the corundum-derived Ni3TeO6 -type structure with large spontaneous polarization (PS) of 67.8 μC cm(-2), complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.<br /> (© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-4095
Volume :
27
Issue :
13
Database :
MEDLINE
Journal :
Advanced materials (Deerfield Beach, Fla.)
Publication Type :
Academic Journal
Accession number :
25677612
Full Text :
https://doi.org/10.1002/adma.201405244