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An alternative to the Sandmeyer approach to aryl iodides.

Authors :
Hu B
Miller WH
Neumann KD
Linstad EJ
DiMagno SG
Source :
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2015 Apr 20; Vol. 21 (17), pp. 6394-8. Date of Electronic Publication: 2015 Mar 10.
Publication Year :
2015

Abstract

Iodoarenes are important synthons for a wide range of organic transformations. Here we report a general strategy to prepare singly iodinated electron-rich aromatic compounds through the intermediacy of diaryliodonium salts. This process, which incorporates a phase separation that greatly simplifies product purification, is an attractive replacement for the Sandmeyer approach to iodoarenes that are otherwise difficult to access.<br /> (© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-3765
Volume :
21
Issue :
17
Database :
MEDLINE
Journal :
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Type :
Academic Journal
Accession number :
25757054
Full Text :
https://doi.org/10.1002/chem.201500151