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Well-defined copper(i) fluoroalkoxide complexes for trifluoroethoxylation of aryl and heteroaryl bromides.

Authors :
Huang R
Huang Y
Lin X
Rong M
Weng Z
Source :
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2015 May 04; Vol. 54 (19), pp. 5736-9. Date of Electronic Publication: 2015 Mar 17.
Publication Year :
2015

Abstract

Copper(I) fluoroalkoxide complexes bearing dinitrogen ligands were synthesized and the structure and reactivity of the complexes toward trifluoroethoxylation, pentafluoropropoxylation, and tetrafluoropropoxylation of aryl and heteroaryl bromides were investigated.<br /> (© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-3773
Volume :
54
Issue :
19
Database :
MEDLINE
Journal :
Angewandte Chemie (International ed. in English)
Publication Type :
Academic Journal
Accession number :
25783796
Full Text :
https://doi.org/10.1002/anie.201501257