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Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Jun 25; Vol. 51 (50), pp. 10194-7. Date of Electronic Publication: 2015 May 27. - Publication Year :
- 2015
-
Abstract
- The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, (57)Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 51
- Issue :
- 50
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 26015999
- Full Text :
- https://doi.org/10.1039/c5cc02550h