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Isolation and Reactivity of 1,4,2-Diazaborole.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2015 Sep 09; Vol. 137 (35), pp. 11274-7. Date of Electronic Publication: 2015 Aug 27. - Publication Year :
- 2015
-
Abstract
- An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC2N2 five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 137
- Issue :
- 35
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 26302247
- Full Text :
- https://doi.org/10.1021/jacs.5b07823