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Isolation and Reactivity of 1,4,2-Diazaborole.

Authors :
Su B
Li Y
Ganguly R
Lim J
Kinjo R
Source :
Journal of the American Chemical Society [J Am Chem Soc] 2015 Sep 09; Vol. 137 (35), pp. 11274-7. Date of Electronic Publication: 2015 Aug 27.
Publication Year :
2015

Abstract

An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC2N2 five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.

Details

Language :
English
ISSN :
1520-5126
Volume :
137
Issue :
35
Database :
MEDLINE
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
26302247
Full Text :
https://doi.org/10.1021/jacs.5b07823