Crystal structure of tetrakis-(acetyl-acetonato)di-chloridodi-μ3-methano-lato-tetra-μ2-methano-lato-tetra-iron(III).

Authors :: Richers CP
Bertke JA
Gray DL
Rauchfuss TB
Source :: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Jul 29; Vol. 71 (Pt 8), pp. 976-9. Date of Electronic Publication: 2015 Jul 29 (Print Publication: 2015).
Publication Year :: 2015
Abstract: The title complex, [Fe4(C5H7O2)4(CH3O)6Cl2] or [Fe4(acac)4(μ2-OMe)4(μ3-OMe)2Cl2] (acac = acetyl-acetonate), crystallizes in the ortho-rhom-bic Pbca space group with one half of the mol-ecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C-H⋯Cl inter-molecular inter-actions result in a two-dimensional layered structure parallel to the ac plane.

Language :: English
ISSN :: 2056-9890
Volume :: 71
Issue :: Pt 8
Database :: MEDLINE
Journal :: Acta crystallographica. Section E, Crystallographic communications
Publication Type :: Academic Journal
Accession number :: 26396769
Full Text :: https://doi.org/10.1107/S2056989015013535

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