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A Critical Compilation of Energy Levels, Spectral Lines, and Transition Probabilities of Singly Ionized Silver, Ag II.

Authors :
Kramida A
Source :
Journal of research of the National Institute of Standards and Technology [J Res Natl Inst Stand Technol] 2013 Apr 15; Vol. 118, pp. 168-98. Date of Electronic Publication: 2013 Apr 15 (Print Publication: 2013).
Publication Year :
2013

Abstract

All available experimental measurements of the spectrum of the Ag(+) ion are critically reviewed. Systematic shifts are removed from the measured wavelengths. The compiled list of critically evaluated wavelengths is used to derive a comprehensive list of energy levels with well-defined uncertainties. Eigenvector compositions and level designations are found in two alternate coupling schemes. Some of the older work is found to be incorrect. A revised value of the ionization energy, 173283(7) cm(-1), equivalent to 21.4844(8) eV, is derived from the new energy levels. A set of critically evaluated transition probabilities is given.

Details

Language :
English
ISSN :
1044-677X
Volume :
118
Database :
MEDLINE
Journal :
Journal of research of the National Institute of Standards and Technology
Publication Type :
Academic Journal
Accession number :
26401429
Full Text :
https://doi.org/10.6028/jres.118.009