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A [3Fe-3S](3+) cluster with exclusively μ-sulfide donors.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Jan 21; Vol. 52 (6), pp. 1174-7. - Publication Year :
- 2016
-
Abstract
- A [3Fe-3(μ-S)](3+) cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 52
- Issue :
- 6
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 26603589
- Full Text :
- https://doi.org/10.1039/c5cc07813j