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A [3Fe-3S](3+) cluster with exclusively μ-sulfide donors.

Authors :
Lee Y
Jeon IeR
Abboud KA
García-Serres R
Shearer J
Murray LJ
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Jan 21; Vol. 52 (6), pp. 1174-7.
Publication Year :
2016

Abstract

A [3Fe-3(μ-S)](3+) cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy.

Details

Language :
English
ISSN :
1364-548X
Volume :
52
Issue :
6
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
26603589
Full Text :
https://doi.org/10.1039/c5cc07813j