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Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2016 Jan 26; Vol. 55 (5), pp. 1690-3. Date of Electronic Publication: 2015 Dec 08. - Publication Year :
- 2016
-
Abstract
- In the presence of stoichiometric or catalytic amounts of [M{N(SiMe3 )2 }2 ] (M=Fe, Co), N-heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)⋅PAr. The formation of (IMe4 )⋅PMes (Mes=mesityl) is also catalyzed by the phosphinidene-bridged complex [(IMe4 )2 Fe(μ-PMes)]2 , which provides evidence for metal-catalyzed phosphinidene transfer.<br /> (© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 55
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 26643712
- Full Text :
- https://doi.org/10.1002/anie.201508303