Back to Search
Start Over
An Enantioselective Assembly of Dihydropyranones through an NHC/LiCl-Mediated in situ Activation of α,β-Unsaturated Carboxylic Acids.
- Source :
-
Chemistry, an Asian journal [Chem Asian J] 2016 Mar 04; Vol. 11 (5), pp. 678-81. Date of Electronic Publication: 2016 Feb 10. - Publication Year :
- 2016
-
Abstract
- A straightforward N-heterocyclic carbene (NHC)/LiCl-mediated synthesis of dihydropyranones from α,β-unsaturated carboxylic acids and 1,3-dicarbonyl compounds was realized through the in situ activation strategy. The key advantages of this protocol include ready availability and high stability of starting materials, good yields, and excellent enantioselectivity.<br /> (© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
- Subjects :
- Carboxylic Acids chemical synthesis
Catalysis
Heterocyclic Compounds chemical synthesis
Methane chemical synthesis
Methane chemistry
Pyrones chemistry
Stereoisomerism
Carboxylic Acids chemistry
Heterocyclic Compounds chemistry
Lithium Chloride chemistry
Methane analogs & derivatives
Pyrones chemical synthesis
Subjects
Details
- Language :
- English
- ISSN :
- 1861-471X
- Volume :
- 11
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- Chemistry, an Asian journal
- Publication Type :
- Academic Journal
- Accession number :
- 26864639
- Full Text :
- https://doi.org/10.1002/asia.201501353