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Crystal structure of (eth-oxy-ethyl-idene)di-methyl-aza-nium ethyl sulfate.

Authors :
Tiritiris I
Saur S
Kantlehner W
Source :
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Nov 07; Vol. 71 (Pt 12), pp. o916. Date of Electronic Publication: 2015 Nov 07 (Print Publication: 2015).
Publication Year :
2015

Abstract

In the title salt, C6H14NO(+)·C2H5SO4 (-), the C-N bond lengths in the cation are 1.2981 (14), 1.4658 (14) and 1.4707 (15) Å, indicating double- and single-bond character, respectively. The C-O bond length of 1.3157 (13) Å shows double-bond character, indicating charge delocalization within the NCO plane of the iminium ion. In the crystal, C-H⋯O hydrogen bonds between H atoms of the cations and O atoms of neighbouring ethyl sulfate anions are present, generating a three-dimensional network.

Details

Language :
English
ISSN :
2056-9890
Volume :
71
Issue :
Pt 12
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Crystallographic communications
Publication Type :
Academic Journal
Accession number :
26870525
Full Text :
https://doi.org/10.1107/S2056989015020678