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Two phenyls are better than one or three: synthesis and application of terminal olefin-oxazoline (TOlefOx) ligands.

Authors :
Zhao YS
Liu JK
He ZT
Tao JC
Tian P
Lin GQ
Source :
Organic & biomolecular chemistry [Org Biomol Chem] 2016 Apr 12; Vol. 14 (15), pp. 3686-9.
Publication Year :
2016

Abstract

A novel terminal olefin-oxazoline ligand was introduced into rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to enones and gave excellent enantioselectivities. The two phenyls proved better than one or three in ligand evaluations.

Details

Language :
English
ISSN :
1477-0539
Volume :
14
Issue :
15
Database :
MEDLINE
Journal :
Organic & biomolecular chemistry
Publication Type :
Academic Journal
Accession number :
27006099
Full Text :
https://doi.org/10.1039/c6ob00460a