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A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations.
- Source :
-
Organic & biomolecular chemistry [Org Biomol Chem] 2016 Apr 28; Vol. 14 (16), pp. 3883-8. Date of Electronic Publication: 2016 Mar 31. - Publication Year :
- 2016
-
Abstract
- The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity.
Details
- Language :
- English
- ISSN :
- 1477-0539
- Volume :
- 14
- Issue :
- 16
- Database :
- MEDLINE
- Journal :
- Organic & biomolecular chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 27031501
- Full Text :
- https://doi.org/10.1039/c6ob00347h