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A three-coordinate Fe(ii) center within a [3Fe-(μ3-S)] cluster that provides an accessible coordination site.

Authors :
Lee Y
Abboud KA
García-Serres R
Murray LJ
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Jul 28; Vol. 52 (59), pp. 9295-8. Date of Electronic Publication: 2016 Jul 01.
Publication Year :
2016

Abstract

A μ3-sulfide bridged triiron cluster(ii,ii,iii) supported by a cyclophane ligand undergoes metal-based reduction to yield an all-ferrous species. The latter complex incorporates a three-coordinate iron center that provides an accessible coordination site to a solvent molecule.

Details

Language :
English
ISSN :
1364-548X
Volume :
52
Issue :
59
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
27363672
Full Text :
https://doi.org/10.1039/c6cc04671a