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A three-coordinate Fe(ii) center within a [3Fe-(μ3-S)] cluster that provides an accessible coordination site.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Jul 28; Vol. 52 (59), pp. 9295-8. Date of Electronic Publication: 2016 Jul 01. - Publication Year :
- 2016
-
Abstract
- A μ3-sulfide bridged triiron cluster(ii,ii,iii) supported by a cyclophane ligand undergoes metal-based reduction to yield an all-ferrous species. The latter complex incorporates a three-coordinate iron center that provides an accessible coordination site to a solvent molecule.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 52
- Issue :
- 59
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 27363672
- Full Text :
- https://doi.org/10.1039/c6cc04671a