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Crystal structure of (E,E)-2',4'-di-hydroxy-aceto-phenone azine di-methyl-formamide disolvate.

Authors :
Li WJ
Han HF
Source :
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2016 Mar 08; Vol. 72 (Pt 4), pp. 467-9. Date of Electronic Publication: 2016 Mar 08 (Print Publication: 2016).
Publication Year :
2016

Abstract

In the title compound {systematic name: 4,4'-[1,1'-(hydrazinediyl-idene)bis-(ethan-1-yl-1-yl-idene)]bis-(benzene-1,3-diol)}, C16H16N2O4·2C3H7NO, the (E,E)-2',4'-di-hydroxy-aceto-phenone azine mol-ecule is centrosymmetric, the mid-point of the N-N bond being located on an inversion centre. All the non-H atoms of the azine mol-ecule are approximately coplanar, the maximum deviation being 0.017 (2) Å. An intra-molecular O-H⋯N hydrogen bond occurs between the azine N atom and the hy-droxy group. In the crystal, azine and di-methyl-formamide solvent mol-ecules are linked by O-H⋯O hydrogen bonds.

Details

Language :
English
ISSN :
2056-9890
Volume :
72
Issue :
Pt 4
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Crystallographic communications
Publication Type :
Academic Journal
Accession number :
27375866
Full Text :
https://doi.org/10.1107/S2056989016003686