Back to Search
Start Over
A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc3N@Ih-C80(-))2 dimers.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Sep 14; Vol. 52 (71), pp. 10763-6. Date of Electronic Publication: 2016 Aug 11. - Publication Year :
- 2016
-
Abstract
- Reduction of scandium nitride clusterfullerene, Sc3N@Ih-C80, by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na(+))}2(Sc3N@Ih-C80(-))2·2.5C6H4Cl2 (1) salt. The Sc3N@Ih-C80˙(-) radical anions are dimerized to form single-bonded (Sc3N@Ih-C80(-))2 dimers.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 52
- Issue :
- 71
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 27511304
- Full Text :
- https://doi.org/10.1039/c6cc05550h