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Arrested α-hydride migration activates a phosphido ligand for C-H insertion.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Dec 22; Vol. 53 (2), pp. 412-415. - Publication Year :
- 2016
-
Abstract
- Bulky tris(carbene)borate ligands provide access to high spin iron(ii) phosphido complexes. The complex PhB(MesIm) <subscript>3</subscript> FeP(H)Ph is thermally unstable, and [PPh] group insertion into a C-H bond of the supporting ligand is observed. An arrested α-hydride migration mechanism suggests increased nucleophilicity of the phosphorus atom facilitates [PPh] group transfer reactivity.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 53
- Issue :
- 2
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 27959360
- Full Text :
- https://doi.org/10.1039/c6cc07864h