Crystal structure of catena -poly[[copper(II)-μ 2 -salicylato-[diaqua-copper(II)]-μ 2 -salicylato] dihydrate].

Authors :: van der Horn JA
Lutz M
Source :: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2017 Jan 20; Vol. 73 (Pt 2), pp. 235-238. Date of Electronic Publication: 2017 Jan 20 (Print Publication: 2017).
Publication Year :: 2017
Abstract: The title compound, {[Cu <subscript>2</subscript> (C <subscript>7</subscript> H <subscript>4</subscript> O <subscript>3</subscript> ) <subscript>2</subscript> (H <subscript>2</subscript> O) <subscript>2</subscript> ]·2H <subscript>2</subscript> O} <subscript> n </subscript> , contains two copper(II) cations in special positions (one on a twofold rotation axis and one on an inversion centre) and the the salicylate ligand in its dianionic form. By four- and six-coordinate metal coordination, chains are formed parallel to [001], which are extended by O-H⋯O hydrogen bonding into sheets extending parallel to (100). These sheets are weakly connected by O-H⋯O hydrogen bonding via the non-coordinating lattice water mol-ecules into a three-dimensional network.

Language :: English
ISSN :: 2056-9890
Volume :: 73
Issue :: Pt 2
Database :: MEDLINE
Journal :: Acta crystallographica. Section E, Crystallographic communications
Publication Type :: Academic Journal
Accession number :: 28217350
Full Text :: https://doi.org/10.1107/S2056989017000883

Full Text Access

Tools